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首页» 过刊浏览» 2019» Vol.4» Issue(4) 440-449     DOI : 10.3969/j.issn.2096-1693.2019.04.039
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基于沥青SARA组成的SBS改性沥青高温性能研究
王勤芳1,曾海2*,杨耀1
1 中国石油大学( 北京) 化学工程与环境学院,北京102249 2 中国石油辽河石化分公司,盘锦 124022
High-temperature performance study of SBS modified asphalt based on SARA fractions
WANG Qinfang1, ZENG Hai2, YANG Yao1
1 College of Chemical Engineering and Environment, China University of Petroleum-Beijing, Beijing 102249, China 2 PetroChina Liaohe Petrochemical Company, Panjin 124022, China

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摘要  本文选取4种不同油源的基质沥青,采用高速剪切法制备苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)改性沥青,通过沥青软化点试验、动态剪切流变试验(DSR)以及多重应力蠕变恢复试验(MSCR)考察了SBS剂量与基质沥青四组分(SARA)组成对改性沥青高温性能的影响。结果发现,改性沥青的高温性能随着SBS剂量的增加而不断增强;基质沥青中沥青质含量高,饱和分含量低时,改性后高温性能更好,而饱和分含量较高时,改性沥青的高温性能随SBS剂量的增加改善速度更快;基质沥青对改性沥青高温性能的影响在SBS剂量较低时显著,而SBS剂量较高时,SBS对改性沥青高温性能的影响更加明显;在DSR试验中SBS剂量为5.0%,低测试角频率(0.1~1.0 rad/s),测试温度为70℃时,III号沥青改性后的抗流动变形能力最好;动态剪切流变试验和多重应力蠕变恢复试验在评价改性沥青高温性能时有较好的相关性。
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关键词 : SBS改性剂;基质沥青;改性沥青;车辙因子;高温性能
Abstract

In this study, four kinds of neat asphalt with different oil sources were selected, and Styrene–Butadiene–Styrene(SBS) modified asphalt was prepared by a high shear method. This study was to investigate the influence of the separation of four SARA fractions and the dosage of SBS polymer on the high temperature performance of modified asphalt in the Softening Point test, Dynamic Shear Rheometer (DSR) and Multiple Stress Creep Recovery (MSCR). The results revealed that the dosage of SBS polymer and SARA fractions had significant effects on the high-temperature performance of modified asphalt. With increasing dosage of SBS polymer, the high-temperature performance of modified asphalt improved continuously. The higher the content of asphaltenes and the lower the content of saturates , the better the high-temperature performance of SBS modified asphalt. The results also indicated that a high saturates content can cause the high-temperature performance of the modified asphalt to improve faster with an increase of the SBS polymer. When the dosage of SBS polymer was low, the neat asphalt has a significant effect on the high temperature performance of the modified asphalt, whereas the influence of SBS polymer is more obvious. The anti-flow deformation ability of III-SBS modified asphalt was the best at high SBS dosage (5.0%), low test oscillation frequency (0.1 ~ 1.0 rad/s) and high test temperature (70 ℃). The dynamic Shear Rheological test and Multiple Stress Creep Recovery test had a good positive correlation on evaluating the SBS modified asphalt.

Key words: SBS modifier, neat asphalt, modified asphalt, high-temperature performance
收稿日期: 2019-12-30     
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通讯作者: zenghai@petrochina.com.cn
引用本文:   
王勤芳, 曾海, 杨耀. 基于沥青SARA组成的SBS改性沥青高温性能研究. 石油科学通报, 2019, 04: 440-449
链接本文:  
WANG Qinfang, ZENG Hai, YANG Yao. High-temperature performance study of SBS modified asphalt based on SARA fractions. Petroleum Science Bulletin, 2019, 04: 440-449.
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