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首页» 过刊浏览» 2021» Vol.6» Issue(3) 516-523     DOI : 10.3969/j.issn.2096-1693.2021.03.042
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无机土壤修复剂对石油烃污染物治理机理研究与验证
刘锐锋
大庆石油管理局钻探工程公司试油测试公司,吉林松原 138000
Research and verification of the treatment mechanism of inorganic soil remediation agent for petroleum hydrocarbon pollutants
LIU Ruifeng
Oil Testing Company of Daqing Oilfield Drilling Engineering Company, CNPC, Songyuan 138000, Jilin, China

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摘要  为了解决油田开发中的石油烃土壤污染问题,创新性地将氧化镁作为修复剂配方成分,对其与粉煤灰、 氧化钙配伍进行石油烃污染修复的可行性,从机理方面进行了研究与分析,认为氧化镁粉具有很大的比表面积 和丰富的孔结构,煤灰提供大量Al、Si等活性位点,氧化镁与氧化钙的碱性作用,会协同将石油烃吸附并形成 稳定的化合物,且该过程具有不可逆性,从而达到石油烃污染土壤修复的目的。为了验证上述机理,以吉林油 田扶余和红岗采油厂原油为污染物,通过调整 3 种成分的配比,实验研究修复剂对石油烃污染土壤的修复效果, 结果表明:对于扶余原油最佳复配质量比为氧化钙:氧化镁:粉煤灰=4:5:3,对于红岗原油最佳复配质量比为氧 化钙:氧化镁:粉煤灰=3:3:2,修复效率在 85%以上。通过机理研究与验证实验,认为本研究的无机土壤修复剂 对石油烃污染物具有很好的去除效果,且修复剂成本低廉,绿色环保,是一种很有发展前景的石油烃污染土壤 修复技术。
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关键词 : 无机修复剂;石油污泥;固化吸附;环境保护;原位修复
Abstract
In order to solve the problem of petroleum hydrocarbon soil pollution in oilfield development, the feasibility of using    
magnesium oxide as a remediation agent formula component, and its compatibility with fly ash and calcium oxide for petroleum    
hydrocarbon pollution remediation, was studied.. According to analysis, it is believed that magnesium oxide powder has a large    
specific surface area and rich pore structure. Coal fly ash provides a large number of active sites such as Al and Si. The alkaline    
effect of magnesium oxide and calcium oxide will synergistically adsorb petroleum hydrocarbons and form a stable mixture. The    
process is irreversible, so it achieves the purpose of remediation of petroleum contaminated soil. In order to verify the above    
mechanism, using crude oil from Fuyu and Honggang Oil Production Plants in Jilin Oilfield as pollutants, by adjusting the ratio    
of three components, the experimental study of the remediation effect of the remediation agent on petroleum contaminated soil    
shows that: the best ratio for Fuyu oil is calcium oxide: magnesium oxide: fly ash is 4:5:3. The best mixed mass ratio for Hong  
gang crude oil is calcium oxide: magnesium oxide: fly ash 3:3:2, and the repair efficiency is 85   %   .. Through mechanism research    
and verification experiments, it is believed that the inorganic soil remediation agent in this study has a good removal effect on    
petroleum hydrocarbon pollutants, and the remediation agent is low in cost and environmentally friendly, and is a promising  
petroleum hydrocarbon contaminated soil remediation technology  


Key words: inorganic repair agent; petroleum sludge; curing adsorption; environmental protection; in-situ remediation
收稿日期: 2021-09-29     
PACS:    
基金资助:
通讯作者: 104732884@qq.com
引用本文:   
刘锐锋. 无机土壤修复剂对石油烃污染物治理机理研究与验证. 石油科学通报, 2021, 03: 516-523 LIU Ruifeng. Research and verification of the treatment mechanism of inorganic soil remediation agent for petroleum hydrocarbon pollutants. Petroleum Science Bulletin, 2021, 03: 516-523.
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